Lampworking can be done with many types of glass, but the most common are soda-lime glass, sometimes called "soft glass" - and borosilicate glass, often called "hard glass". Leaded glass tubing was commonly used in the manufacture of neon signs, although its use has been fading due to environmental concerns and health risks.
Different colours of glass must be carefully selected for compatibility with each other, both chemically (more of a concern with soft glass than borosilicate) and in terms of coefficient of thermal expansion (COE). Glass with incompatible COE mixed together, can create powerful stresses within a finished piece as it cools, cracking or violently shattering the piece. Different major types of glass, e.g., borosilicate and soda-lime glass are not compatible with each other. Chemically, some colours can react with each other when melted together. This may cause desirable effects in colouration, metallic sheen, or result in an aesthetically pleasing crazing effect. It also can cause undesirable effects such as unattractive discolouration, bubbling, or devitrification. The atmosphere of the flame has an effect on the glass surface, it can also cause discolouration, a metallic sheen, depending on whether the flame is oxidizing (more oxygen) or reducing (more fuel) and the type of glass used. Moving and shaping the glass whilst it is too cool can cause devitrification.
Borosilicate glass is considered more forgiving to work with, as its lower COE makes it less liable to crack during flameworking than soda-lime glass. In comparison to soda-lime glass, it has a narrower working temperature range, has in the past had fewer available colours (this situation has now changed somewhat, there are many businesses currently manufacturing coloured borosilicate glass), and is considerably more expensive. Also, its working range is at higher temperatures, requiring hotter torches and the use of oxygen instead of air. In addition to producing a hotter flame, the use of pure oxygen allows more control over the flame's oxidizing or reducing properties, which is necessary because some colouring chemicals in borosilicate glass react with any remaining oxygen in the flame to produce different surface colours, depending how much, or little oxygen is present.